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steroid Most of the complexes studied have the general formula Ir(N^C^N)(N^C)X, where N^C^N represents a terdentate ligand based on 1 steroid side effects,3 di(2 pyridyl)benzene; N^C a bidentate ligand such as ppy; and X is a monodentate ligand such as chloride, cyanide, thiocyanate or an acetylide. The synthetic methodology developed involves reaction of the N^CH^N proligand with iridium(III) chloride to give a dimer of the form [Ir(N^C^N)Cl( Cl)]2, which is cleaved upon treatment with a bidentate N^CH ligand. The one remaining chloride ligand can then be exchanged for other monodentate ligands through silvercatalysed metathesis. steroid
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